Miki Hasegawa

College of Science and Engineering, Aoyama Gakuin University
Professor
A03
A03-02

Research AreasPhotochemistry of Coordination Compounds

Development of luminescence properties by the manipulation of interface in Soft Crystals

Keywords
Coordination Compound, Soft Crystal, Luminescence, Function by hybridization, Thin film/Interface
Co-Researcher
Co-Investigator: Masamichi Yamanaka (Faculty of Science, Shizuoka University, Meiji Pharmaceutical University, Professor)
Co-Investigator: Chao-Nan Xu (National Institute of Advanced Industrial Science and Technology (AIST), Associate Professor)
Co-Researcher: Hitomi Ohmagari (College of Science and Engineering, Aoyama Gakuin University, Assistant Professor)
Co-Researcher: Nicolas Marets (College of Science and Engineering, Aoyama Gakuin University, Research Associate)

Research Outline

In the photochemical phenomenon, information concerning the molecules themselves and their aggregation is reflected sharply. In this study, we aim to develop luminescent material based on lanthanide compounds for new possible classification phase among three phases, such as transfer from the water surface to the solid substrate [LB film]or sol/gel[Hydrogel]. We focus on the orientation of the soft crystal of the interface complex and its photo properties by utilizing the interface of the difficult system. Luminescence of rare earths is accelerated via the excited state of the ligand, and therefore its mechanism is different from electronic absorption and energy relaxation (luminescence) of common organic molecules. For that reason, nobody knows the principle to establish the control of “polarized luminescence” and “long-lasting of luminescence”. Therefore, in this project, we will promote the research with the aim of exploiting rare-earth complexes and developing new optical properties by interfacial control of soft crystals.

Interface molecular layers at water/air to induce polarized luminescence.
Adsorption ability and luminescence of hydrogels with Tb

Representative Achievements

  • “Water-soluble lanthanide complexes with a helical ligand modified for strong luminescence in a wide pH region”, S. Ogata, T. Shimizu, T. Ishibashi, Y. Ishiyone, M. Hanami, M. Ito, A. Ishii, S. Kawaguchi, K. Sugimoto and M. Hasegawa, New J. Chem., 2017, 41, 6385-6394.
    DOI: 10.1039/c7nj01444a
  • “Organic Dye Adsorption by Amphiphilic Tris-Urea Supramolecular Hydrogel”, J. Takeshita, Y. Hasegawa, K. Yanai, A. Yamamoto, A. Ishii, M. Hasegawa, and M. Yamanaka, Chem. Asian J., 2017, 16, 2029- 2032 |
    DOI: 10.1002/asia.201700878
  • “Solar-pumping Upconversion of Interfacial Coordination Nanoparticles”, A. Ishii, and M Hasegawa, Sci. Rep., 2017, 7, 41446 |
    DOI: 10.1038/srep41446
  • “Polymorphism-based luminescence of lanthanide complexes with a deuterated 1,10-phenantholine”, S. Ogata, A. Ishii, C. Lu, T. Kondo, N. Yajima, M Hasegawa, J. Photochem. Photobio. A, 2017, 334, 55–60.
    DOI: 10.1016/j.jphotochem.2016.10.031
  • “The Ethanol-induced Interfacial Reduction of a Europium Complex on SiO2 Nanoparticles”, A. Ishii, and M. Hasegawa, Chem. Lett., 2016, 45, 1265-1267.
    DOI: 10.1246/cl.160698
  • “An Interfacial Europium Complex on SiO2 Nanoparticles: Reduction-Induced Blue Emission System”, A. Ishii, M. Hasegawa, Sci. Rep., 2015, 5, 11714.
    DOI: 10.1038/srep11714

Publications

Category

Academic papers/reviewed

  1. "Helicate Lanthanide Complexes: The Luminescent Elements" M. Hasegawa and H. Ohmagari, Chemistry Letters, 2020, in press.
  2. "Mixed Tb/Dy coordination ladders based on tetra(carboxymethyl)chiacalix[4]arene: a new avenue towards luminescent molecular nanomagnets" A.S. Ovsynnikov, I. V. Khariushin, S. E. Solovieva, I. S. Antipin, H. Komiya, N. Marets, H. Tanaka, H. Ohmagari, M. Hasegawa, J. J. Zakrzewski, Chorazy, N. Kyritsakas, M. W. Hosseini and S. Ferlay, RSC Advances, 2020, 10, 11755-11765.
  3. "Elements in Sports: From IYPT2019 to TOKYO2020" M. Hasegawa, M. Yamanaka, O. Miyamae, Hayanon Scientific Manga Artist, Chemistry International, 2020, 1, 5-7.
  4. "Chiroptical Spectroscopic Studies on Lanthanide Complexes with Valinamide Derivatives in Solution" M. Hasegawa, D. Iwasawa, T. Kawaguchi, H. Koike, A. Saso, S. Ogata, A. Ishii, H. Ohmagari, M. Iwamura and K. Nozaki, Chem Plus Chem, 2020, 85, 294-300.
  5. "Lanthanide-oligomeric Brush-Films: From Luminescence Properties to Structure Resolution" N. Marets, S. Kanno, S. Ogata, A. Ishii, S. Kawaguchi and M. Hasegawa, ACS Omega, 2019, 4 (13), 15512-15520.
  6. "Strong Luminescent Europium Complexes Induced by the Unprecedented Anti-chelate Effect of Acyl Groups on a N6-Hexadentated Ligand" S. Ogata, H. Komiya, N. Goto, R. Tanabe, K. Sugimoto, S. Kawaguchi, K. Goto, M. Hatanaka, A. Ishii and M. Hasegawa, Chemistry Letters, 2019, 48(6), 593-596.
  7. "Europium amphiphilic naphthalene based complex for the enhancement of linearly polarized luminescence in Langmuir-Blodgett films" K. Yoshihara, M. Yamanaka, S. Kanno, S. Mizushima, J. Tsuchiyagaito, K. Kondo, T. Kondo, D. Iwasawa, H. Komiya, A. Saso, S. Kawaguchi, K. Goto, S. Ogata, H. Takahashi, A. Ishii and M. Hasegawa, New Journal of Chemistry, 2019, 43, 6472-6479.
  8. "Soft Crystals‐Flexible Response Systems with High Structural Order" M. Kato, H. Ito, M. Hasegawa, K. Ishii, Chemistry – A European Journal, 2019, 25, 5105-5112.
  9. "Making graphene luminescent by adsorption of an amphiphilic europium complex" Y. Hara, K. Yoshihara, K. Kondo, S. Ogata, T. Watanabe, A. Ishii, M. Hasegawa, S. Koh, Appl. Phys. Lett., 2018, 112, 173103/1-5.
  10. "Alkyl chain elongation and acyl group effects in a series of Eu/Tb complexes with hexadentate π-electronic skeletons and their enhanced luminescence in solutions" S. Ogata, N. Goto, A. Ishii, M. Hatanaka, K. Yoshihara, R. Tanabe, K. Kayano, R. Magaribuchi, K. Goto, M. Hasegawa, Dalton Trans., 2018, 47, 7135-7143.
  11. "Enzymatic hydrolysis-induced degradation of a lactose-coupled supramolecular hydrogel" S. Akama, T. Maki, M. Yamanaka, Chem. Commun., 2018, 54, 8814-8817.
  12. "Preparation of Tetrazole-fused π-Conjugated Molecules and Their Fluorescence Behavior" T. Hata, Y. Hayashi, Y. Hasegawa, M. Iwai, A. Ishii, M. Hasegawa, M. Shigeta, H. Urabe, Chem. Lett., 2019, 48, 662-665.
  13. "Gelation and luminescence of lanthanide hydrogels formed with deuterium oxide" Y. Zama, K. Yanai, J. Takeshita, A. Ishii, M. Yamanaka, M. Hasegawa, RSC Advances, 2019, 9, 1949-1955.
  14. "Trap-controlled mechanoluminescent materials" J. Zhang, X. Wang, G. Marriott, C. Xu, Prog. Mat. Sci., 2019, 103, 678-742.
  15. "Multicolor Upconversion Luminescence of Dye-Coordinated Er3+ at the interface of Er2O3 and CaF2 nanoparticles" A. Ishii, Y. Adachi, A. Hasegawa, M. Komaba, S. Ogata, M. Hasegawa, Sci. Tech. Adv. Mater., 2019, 20, 44-50.
  16. "Gabriel synthesis of hexakis(aminomethyl)benzene and its derivatization" J. Masuda, S. Kondo, Y. Matsumoto, M. Yamanaka, ChemistrySelect, 2018, 3, 6112-6115.
  17. "Scalable elasticoluminescent strain sensor for precise dynamic stress imaging and onsite infrastructure diagnosis" L. Liu, C.-N. Xu, A. Yoshida, D. Tu, N. Ueno, S. Kainuma, Adv. Mat. Tech., 2019, 4, 1800336 (1) - (10).
  18. "Sustainable mechanoluminescence by designing a novel pinning trap in crystals" D. Tu, R. Hamabe, C.-N. Xu, J. Phys. Chem. C, 2018, 122, 23307-23311.
  19. "Piezo-photonics: from fundamentals and materials to applications" H. Jianhua, C.-N. Xu, MRS Bulletin, 2018, 43, 965-969.
  20. "Synthesis of a bis-urea dimer and its effects on the physical properties of an amphiphilic tris-urea supramolecular hydrogel" H. Sawada, M. Yamanaka, Chem. Asian J., 2018, 13, 929-933.
  21. "Sensitive Photodetection with Photomultiplication Effect in an Interfacial Eu2+/3+ Complex on a Mesoporous TiO2 Film" A. Ishii, T. Sakai, R. Takahashi, S. Ogata, K. Kondo, T. Kondo, D. Iwasawa, S. Mizushima, K. Yoshihara, M. Hasegawa, ACS Appl. Mater. Interfaces, 2018, 10, 5706-5713.
  22. "The Enhanced Intramolecular Energy Transfer and Strengthened ff Luminescence of a Stable Helical Eu Complex in Ionic Liquids" Y. Hasegawa, A. Ishii, Y. Inazuka, N. Yajima, S. Kawaguchi, K. Sugimoto and M. Hasegawa, Molecules, 2018, 23(2), 55-70.
  23. "Synthesis of a C3-symmetric tris-imine via dynamic covalent bond formation between a trialdehyde and a triamine" K. Nakada, S. Kondo, Y. Matsumoto, M. Yamanaka, Tetrahedron Lett., 2017, 58, 4612-4616.

Review article, commentary, criticism etc.

  • "Development hybrid mechanoluminescence materials for visualization of structural health" C. Xu, 2017, 80-81.

Attend international conferences and overseas dispatch

  1. "Photo-energy conversion in lanthanide-based interfacial coordination nanoparticles" A. Ishii, 第13回 化学的にプログラムされた合成色素類の超分子ナノ科学
    Thirteenth International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments (SNCPP17) (Kusatu, Japan, Jun. 23-25, 2017)
  2. "Photoluminescence properties of helicate lanthanide complexes" M. Hasegawa, A. Ishii, M. Hatanaka (Invited), PS-IWASOM'2017 (Phosphor Safari and The SIXTH International Workshop on Advanced Spectroscopy and Optical Materials) (Gdańsk, Poland, Jul. 14-14, 2017)
  3. "Luminescence and nature of electrons of a series of helicate lanthanide complexes " M. Hasegawa (Invited), The 28th International Conference on Photochemistry (ICP 2017) (Strasbourg, France, Jul. 16-21, 2017)
  4. "Deuteration Effects on the Intramolecular Energy Transfer and Luminescence of Lanthanides Coordinating 1,10-Phenanthroline" M. Hasegawa (Invited), Energy 7 (Manchester, UK, Aug. 13-16, 2017)
  5. "Molecular Design of Luminescence Lanthanide Complexes for the Hybridization as Layered Materials" M. Hasegawa (Invited), Symposium of Advanced Materials (Stockholm, Sweden, Aug. 17-17, 2017)
  6. "Luminescence mechanism of a series of helicate Eu complexes in the mesocrystals" S. Ogata, T. Tanabe, A. Ishi, Y. Oaki, H. Imai, M. Hasegawa, Symposium of Advanced Materials (Stockholm, Sweden, Aug. 17-17, 2017)
  7. "Molecular design strategies for the enhancement of the on-demand luminescence of rare earth compounds" M. Hasegawa (Invited), European Advanced Materials Congress (EAMC- 2017) (Stockholm, Sweden, Aug. 22-24, 2017)
  8. "Luminescence mechanism of a series of helicate Eu complexes in the mesocrystal" S. Ogata, European Advanced Materials Congress (EAMC- 2017) (Stockholm, Sweden, Aug. 22-24, 2017)
  9. "Water-soluble lanthanide complexes with a helicate pi-electronic system for strong luminescence in a wide pH region" M. Hasegawa, Y. Ishiyone, A. Ishi, M. Hasegawa, International Conference on Biological, Chemical and Environmental Sciences (Tokyo, Japan, Dec. 21-22, 2017)"Water-soluble lanthanide complexes with a helicate pi-electronic system for strong luminescence in a wide pH region" M. Hasegawa, Y. Ishiyone, A. Ishi, M. Hasegawa, International Conference on Biological, Chemical and Environmental Sciences (Tokyo, Japan, Dec. 21-22, 2017)
  10. "Luminescent-Plasmonic Core-Shell Nanostructures Based on Lanthanide Doped Fluorides" S. Goderski, M. Runowski, M. Hasegawa, S. Lis, International Conference on Biological, Chemical and Environmental Sciences (Tokyo, Japan, Dec. 21-22, 2017)
  11. "Dye Adsorption Behavior of Tris-Urea Supramolecular Hydrogel" M. Yamanaka (Invited), International Symposium on Pure & Applied Chemistry (ISPAC) 2017 (Ho Chi Minh, Vietnam, Jun. 8-10, 2017)
  12. "Dye Adsorption to Supramolecular Hydrogel of Amphiphilic Tris-Urea" M. Yamanaka, J. Takeshita, IUMRS-ICAM 2017 (Kyoto, Japan, Aug. 27-Sep. 1, 2017)"Dye Adsorption to Supramolecular Hydrogel of Amphiphilic Tris-Urea" M. Yamanaka, J. Takeshita, IUMRS-ICAM 2017 (Kyoto, Japan, Aug. 27-Sep. 1, 2017)
  13. "Recent Progress in Development of Mechanoluminescence: From Elasticoluminescence to Multipiezo" C. Xu (Plenary Lecture), 3nd International Conference on Mechanoluminescence and Novel Structural Health Diagnosis (Hong Kong, China, Dec. 15-17, 2017)
  14. "Tailoring bandgap and trap distribution to improve mechanoluminescence in Sr3Sn2O7:Sm3+ layered perovskite oxide" J. Li, C. Xu, D. Tu, X. Chai, X. Wang, L. Liu, E. Kawasaki (Invited), 3nd International Conference on Mechanoluminescence and Novel Structural Health Diagnosis (Hong Kong, China, Dec. 15-17, 2017)
  15. "Controllable conversion of the mechanical quenching and mechanoluminescence in phosphorescent CaZnOS:Cu" D. Tu, C. Xu, Y. Fujio (Invited), 3nd International Conference on Mechanoluminescence and Novel Structural Health Diagnosis (Hong Kong, China, Dec. 15-17, 2017)
  16. "Statistical Approach for Extraction of Mechanoluminescent Pattern" N. Ueno, R. Gotoh, T. Nagashima, C. Xu (Invited), 3nd International Conference on Mechanoluminescence and Novel Structural Health Diagnosis (Hong Kong, China, Dec. 15-17, 2017)
  17. "LiNbO3:Pr3+: A Multipiezo Material with Simultaneous Piezoelectricity and Sensitive Piezoluminescence" X. Zhang, C. Xu, D. Tu (Invited), 3nd International Conference on Mechanoluminescence and Novel Structural Health Diagnosis (Hong Kong, China, Dec. 15-17, 2017)
  18. "Near-infrared mechanoluminescent material for stress imaging in the optical window of biological tissue" L. Zheng, D. Tu, E. Kawasaki, N. Ueno, C. Xu, 3nd International Conference on Mechanoluminescence and Novel Structural Health Diagnosis (Hong Kong, China, Dec. 15-17, 2017)
  19. "Novel mechanoluminescence materials with a Ruddlesden-Popper-type layered perovskite structure" Y. Ishiyone, D. Tu, C. Xu, 3nd International Conference on Mechanoluminescence and Novel Structural Health Diagnosis (Hong Kong, China, Dec. 15-17, 2017)
  20. "Improvement of Elastico-Luminescence property in LiNbO3:Pr3+ by composition control" J. Hirotsu, D. Tu, M. Fujihara, R. Wang, X. Zheng, C. Xu, 3nd International Conference on Mechanoluminescence and Novel Structural Health Diagnosis (Hong Kong, China, Dec. 15-17, 2017)
  21. "Towards standardization of mechanoluminescence technology" H. Tateyama, N. Ueno, K. Hyodo, C. Xu, International Standardization Meeting (Hong Kong, China, Dec. 17-17, 2017)

Related Website(s)
Contact
hasemiki[at]chem.aoyama.ac.jp